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Abundant mineral content and characteristic IR absorption bands

1 Abundant mineral content and characteristic IR absorption bands [Pg.102]

2 Comparison of pyrolysis mass spectra for aqueous soil extract, fulvic acid, and water-soluble humic acid [Pg.104]

and 84 m/z (ethene to hexene). They were probably derived from aliphatic acids, as evidenced by the fragment series at 43, 57, [Pg.104]

Soil fulvic acid (Fig. 5.2(B)) shows dominant signals similar to those observed in a complex polysaccharide spectrum (ref. 359), with peaks at 68, 82, 84, 96, 98, 110, 112, 114, 126, and 128 m/z. In addition, nitrogen-containing fragments are low. Evidence of polysaccharide is also shown in the spectrum of a water-soluble fraction of humic acid (Fig. 5.2(C )), isolated by gel filtration (ref. 362). However, the presence of homologous ion series of sulfides (34, 48 m/z), pyrroles (67, 81, 95 m/z), pyridine (79 m/z), benzenes (78, 106 m/z), phenols (94, 108, 122 m/z), indole (117 m/z), and lignin-derived units (124, 138, 150 m/z) with variable intensity, [Pg.104]




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Absorption bands

Absorption characteristics

Banded minerals

Banding characteristics

Characteristic absorption band

Characteristic bands

IR absorption

IR bands

Mineral absorption

Mineral characteristics

Mineral content

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