Zusman

From these potential energy curves, the reaction rate can be calculated with the aid of Kramers theory. In the limit of a high solvent friction y, the rate is given by Kramers [1940] and Zusman [1980]... 

Zusman LD. 1980. Outer-sphere electron transfer in polar solvents. Chem Phys 49 295-304. 

Braun, S., Rappoport, S., Zusman, R., Avnir, D. and Ottolenghi, M. (1990) Biochemically active sol-gel glasses the trapping of enzymes. Materials Letters, 10, 1-5. 

Zusman R., Rottman C., Ottolenghi M., Avnir D., Doped sol-gel glasses as chemical sensors, J. Non-Cryst. Solids 1990 122 107-109. 

R to P is slow, even when the isoenergetic conditions in the solvent allow the ET via the Franck-Condon principle. The TST rate for this case contains in its prefactor an electronic transmission coefficient Kd, which is proportional to the square of the small electronic coupling [28], But as first described by Zusman [32], if the solvation dynamics are sufficiently slow, the passage up to (and down from [33]) the nonadiabatic curve intersection can influence the rate. This has to do with solvent dynamics in the solvent wells (this is opposed to the barrier top description given above). We say no more about this here [8,11,32-36]. 

The role of solvent dynamics in the electron transfer reaction at a Pt electrode was discussed utilizing the theory of Zusman. In this work, ° the solvent-dependent rate constant for the electron transfer reaction at an electrode was given as... 

McCleary, W.R. Zusman, D.R. FrzE of Myxococcus xanthus is homologous to both CheA and CheY of Salmonella typhimurium. Proc. Natl. Acad. Sci. USA, 87, 5898-5902 (1990)... 

Excited State Charge Transfer. Our goal here is to discuss aspects of ET theory that are most relevant to the charge transfer processes of excited molecules. One important point is that often the solvent relaxation is not well modeled with a single t, but rather a distribution of times apply. This subject has been treated by Hynes [63], Nadler and Marcus [65], Rips and Jortner [66], Mukamel [67], Newton and Friedman [68], Zusman [62], Warshel [71], and Fonseca [139], We also would like to study ET in the strongly adiabatic regime since experimental results on BA indicate this is the correct limit. Finally, we would like to treat the special case of three-well ET, which is the case for BA. 

Zusman RM, Rubin RH, Cato AE, Cocchetto DM, Crow JW, Tolkoff-Rubin N. Hemodialysis using prostacyclin instead of heparin as the sole antithrombotic agent. N Engl J Med 1981 304(16) 934-9. 

Zusman R. Patients with uncontrolled hypertension or concomitant hypertension and benign prostatic hyperplasia. Clin Cardiol. 2004 27 63-69. 

---