Zirconium IV Sulfide

Zirconium sponge (1.82 g., 0.020 mole) and resublimed sulfur (1.34 g., a slight excess over 0.040 mole) are charged into the transport tube. The procedures for adding iodine (5 mg./ml. of ampule volume) and heating that are described in the TiS2 

Mellor, A Comprehensive Treatise on Inorganic and Theoretical Chemistry, Vol. 7, p. 469, Longmans, Green Co., Ltd., London, 1927, contains an extensive list of early references. 

Schafer, Chemical Transport Reactions, Academic Press, Inc., New York, 1961. 

ANHYDROUS MOLYBDENUM HALIDES AND OXIDE HALIDES—A SUMMARY 

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Titanium(IV) sulfide, zirconium (IV) sulfide, hafnium(IV) sulfide, and tin(IV) sulfide constitute a group of isostructural compounds that can be prepared by similar methods. A... 

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