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Molybdenum halides anhydrous

ANHYDROUS MOLYBDENUM HALIDES AND OXIDE HALIDES—A SUMMARY... [Pg.165]

Preparation of the anhydrous molybdenum(IV) halides is a difficult task because of the relative ease of disproportionation... [Pg.54]

BTF is prepared industrially from toluene in two synthetic steps 1) free radical perchlorination of the methyl group, followed by 2) fluorine/chlorine exchange of the three chlorine atoms with anhydrous hydrogen fluoride (Scheme 1). The chlorination step may be catalyzed by light of suitable wavelength (UV) and is conveniently carried out in the liquid phase. The fluoride/chloride exchange can be catalyzed by the presence of metal halide compounds, such as pentahalide (Cl, F) salts of antimony and molybdenum, and is effected under a variety of... [Pg.81]

Hexacarbonyls of chromium, molybdenum and tungsten form (yields of 92,76, and 92%, respectively) by treatment of the corresponding anhydrous metal halide with AlEt3 and CO in diethyl ether . Details of this method, as applied to Cr(CO)g, are available . [Pg.479]


See other pages where Molybdenum halides anhydrous is mentioned: [Pg.790]    [Pg.139]    [Pg.515]    [Pg.86]    [Pg.54]    [Pg.689]    [Pg.681]    [Pg.729]    [Pg.823]    [Pg.668]    [Pg.763]    [Pg.735]    [Pg.727]    [Pg.761]    [Pg.681]   
See also in sourсe #XX -- [ Pg.12 , Pg.165 , Pg.166 , Pg.167 ]

See also in sourсe #XX -- [ Pg.12 , Pg.165 , Pg.166 , Pg.167 ]

See also in sourсe #XX -- [ Pg.12 , Pg.165 , Pg.166 , Pg.167 ]

See also in sourсe #XX -- [ Pg.12 , Pg.165 , Pg.166 , Pg.167 ]




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Halides , anhydrous

Molybdenum halides

Molybdenum oxide halides , anhydrous

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