It is interesting to note that if the starting point had been Eq. 3.124, a trivial result would have been obtained because the overall mass-continuity equation has already been invoked through the introduction of the substantial derivative. The summation of Eq. 3.124 would simply reveal that zero equals zero. [Pg.97]

In Eq. (25) the first term represents the contribution to the entropy from rotational isomerism without regard to lattice interferences, and 0.86 R the decrease in entropy due to packing on the lattice . The values of A SD calculated by difference were found to lie between 1.7 and 2.0 cal deg-1 mole-1 for polyethylene, polyoxymethylene and polytetrafluoro-ethylene. According to this theory when E equals zero,/equals Vs instead of V3 as one would expect if pentane interference did not occur. Assuming that A SD is compensated for by 0.86 R, values of A SR computed from the first term on the right hand side of Eq. (25) agreed farily well with the observed values of (A S,)v. [Pg.241]

The zero equal expressions mean the accomplishment of the stationary state after that, there are no changes to dxP (dxJ stationary = 0). This state, as before, corresponds to those zero fluxes that are induced by the inter nal thermodynamic forces and relate to time variable values of internal thermodynamic parameters. [Pg.119]

It is immediately apparent that (248) will give the correct zero-frequency xc potential value for Harmonic Potential Theorem motion. For this motion, the gas moves rigidly implying X is independent of r so that the compressive part, Hia, of the density perturbation from (245) is zero. Equally, for perturbations to a uniform electron gas, Vn and hence nn, is zero, so that (248) gives the uniform-gas xc kernel fxc(

Since the first term on the right-hand side is the quotient of squared terms, it is always positive or zero. Zero equality is obtained only when the distribution is monodispcrse, and then equals zero. [Pg.57]

In Eq. 4.8, wi is taken to be a large positive number (depending on the value of the original objective function) in case the constraint is violated else it is assigned a value of zero. Equality constraints can be handled in a similar manner. The results for this problem for the 40 generation are shown in Eig. 4.4. The computational parameters used are Istrmg = 10,... [Pg.98]

In both the Flory and LF theories, the cohesive energy density of a fluid at absolute zero equals its characteristic pressure, P. It is, therefore, convenient to define a dimensionless parameter Ag in terms of the characteristic pressures of the pure components ... [Pg.177]

If we take the original FID and add an equal number of zeroes to it, the corresponding spectrum has double the number of points and so the line is represented by more data points. This is illustrated in Fig. 4.14 (b). Adding a set of zeroes equal to the number of data points is called one zero filling . [Pg.62]

Absolute temperature. A temperature on the Kelvin temperature scale (with zero equal to —273°C). [Pg.220]

In 1848 William Thomson (1824—1907), a British physicist whose title was Lord Kelvin, proposed an absolute-temperature scale, now known as the Kelvin scale. On this scale 0 K, called absolute zero, equals —273.15 °C. (Section 1.4) In terms of the Kelvin scale, Charies s law states The volume of a fixed amount of gas maintained at constant pressure is direcdy proportional to its absolute temperature. Thus, doubling the absolute temperature causes the gas volume to double. Mathematically, Charles s law takes the form... [Pg.390]

There is always one negative and one positive pole, which are independent of the value of Rq. For the resistance / o = 10 (Fig. 13.18a) there are two negative zeros, and the system is stable. For Rq = 100 Q. raie zero equals zero. In this case, the low-frequency impedance becomes zero, which indicates a saddle-node bifurcation. At Rq> 100 2, a positive zero appears, and the system is no longer stable. [Pg.290]

The integral on the right of Equation 6-76 is non-zero (equal to one) only whenk= i. [Pg.143]

© 2019 chempedia.info