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With sodium tnfluoroacetate

Aliphatic Ct, (A-dietus, activated with ester groups at both terminal positions, undergo tnfluoromethylation with cyclization durmg electrochemical oxidation with sodium tnfluoroacetate [79] (equation 70). [Pg.346]

Sodium nitrite in dimethylformamide acts as a nucleophile and reacts with perfluoropropene to generate a perfluoroalkyl nitrite anion The intermediate carbanion undergoes intramolecular nitrosation with loss of carbonyl difluoride to give tnfluoroacetic acid upon hydrolysis [5] (equation 6)... [Pg.399]


See other pages where With sodium tnfluoroacetate is mentioned: [Pg.110]    [Pg.946]    [Pg.946]   
See also in sourсe #XX -- [ Pg.480 , Pg.481 ]

See also in sourсe #XX -- [ Pg.480 , Pg.481 ]

See also in sourсe #XX -- [ Pg.480 , Pg.481 ]




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Sodium tnfluoroacetate

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