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With bipy-diol

However, oxidation with H2O2 in acetone resulted in a high diol selectivity with an equilibrium mixture of the cis- and trans-diols, illustrating the role of the residual acidity of the support The reaction is suggested to occur via heterolyhc cleavage of the vanadium peroxo species. Less than 0.5% leaching of the bipy complex was observed over 50 h of operation. [Pg.213]

Tubocurarine complexes. Reaction of Os(bipy)(Cl4 with (—)-tubocurarine (L) gave the binuclear complex [Cl(bipy)Os(LL)Os(LL)Os(bipy)Cl], dichloro-/i-[l,4-cyclohexylbis(2,2, 2"-terpyridyl)-6"-methyl)-l,4-diol]bis(2,2 -pyridyl)diosmium(II) dichloride. The two coordinated chloro ligands can be replaced by pyridine on refluxing this with the complex in aqueous solution. The former complex has potent curariform biological activity and there are possible applications as stains for electron microscopy for the complexes. ... [Pg.544]

See other pages where With bipy-diol is mentioned: [Pg.182]    [Pg.182]    [Pg.411]    [Pg.214]    [Pg.702]    [Pg.172]    [Pg.544]    [Pg.4023]    [Pg.582]    [Pg.168]    [Pg.4022]    [Pg.3998]    [Pg.247]    [Pg.134]    [Pg.379]    [Pg.150]    [Pg.104]    [Pg.38]    [Pg.65]   
See also in sourсe #XX -- [ Pg.411 ]



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