Werner-Miolati series

Complexes of the Werner-Miolati series are examples where the oxidized and reduced forms bear identical charges, Eq. 1.24 and 1.25 ... 

Table 1 shows a comparison of the formulas and predicted numbers of ions for the transition series [Co(NH3)6](N02)3. .. K3[Co(N02)6] according to the two theories, and Figure 1 shows the results of Werner s first published experimental work in support of his coordination theory, a study of conductances carried out in collaboration with his friend and former fellow student Arturo Miolati (1869—1956).63... 

In their second article on the conductances of complexes, Werner and Miolati showed the complete agreement in magnitude, variation and pattern between their experimentally measured conductances and those predicted according to the coordination theory. The graph of experimentally measured conductances for the [Co(NH3)g]Cl3. .. K3[Co(N02)e] transition series (Figure 1) agreed completely with the numbers of ions pre cted according to the coordination theory (Table 1). The conductance results were also concordant with the number of masked and unmasked acid radicals. Furthermore, in its explanation of anionic complexes and its demon-... 

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