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Wavefunctions in LSJ-, intermediate, and .-coupling

If spin-orbit effects are negligible, LSJ-coupling can be applied, and the two wavefunctions for J = 1 and M = 1 are given by [Pg.310]

In the limiting case of strong spin-orbit interactions, /s)-coupled single-particle orbitals have to be used. With the help of equs. (7.42)-(7.44) they can be traced back to the common spin orbitals, giving [Pg.310]

The relation between the wavefunctions (p j and q w of the two extreme coupling cases can be worked out using the representations directly in the Slater determin-antal wavefunctions, equs. (7.95) and (7.96), or alternatively, using the coupling transformation in equ. (7.52). In both cases one gets [Pg.310]

For intermediate coupling, however, the wavefunction has to be derived from a [Pg.310]




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Coupling intermediate

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