Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Wacker process limitations

In addition to the cr-v equilibrium, an exchange between the n complex (45) and free acetaldehyde has been demonstrated using, 4C-labeled acetaldehyde (46, 48). After 45 hours at room temperature, 0.46% exchange was observed. While this appears quite small, one must remember that the free vinyl alcohol/acetaldehyde ratio has been estimated to have an upper limit of only 10-7 and that in the Wacker Process the equilibrium between 7r-coordinated and free vinyl alcohol would be shifted considerably in favor of free vinyl alcohol by the overpressure of ethylene. Thus, the behavior of the ir-vinyl alcohol complexes (45) and (48) seem to support the importance of such complexes as intermediates in the Wacker and similar olefin oxidation processes. [Pg.244]

Direct palladation of C-H bonds can be achieved by treatment of, for example, electron-rich arenes with Pd(II) salts (see also Section8.11). After cross-coupling via reductive elimination the resulting Pd(0) must be reoxidized to Pd(II) if Pd-catalysis is the aim [85], Reoxidation of Pd(0) with Cu or Ag salts (as in the Wacker process) is not always well suited for C-C bond-forming reactions [86], but other oxidants, for example peroxides, have been used with success (Scheme8.9). The required presence of oxidants in the reaction mixture limits the scope of these reactions to oxidation-resistant starting materials. [Pg.287]

This article will be concerned with the mechanisms of some of these reactions and with some of the general principles that underly this relatively new and rapidly developing field of chemistry. The subject in question has attracted much interest in recent years both because of the novelty of much of the chemistry it reveals and because of its potential practical applications, exemplified by at least two processes (the Oxo and Wacker processes) which have already achieved considerable industrial importance. The possible relevance of many of the catalytic reactions in this field as model systems for related heterogeneous and enzymic process also lends interest to the subject although attempts to exploit this theme have thus far met with only limited success. [Pg.2]

When media other than water are used, different but related processes operate. Thus, the oxidation of ethylene in acetic acid can be directed to give vinyl acetate, ethylene glycol acetate, or 2-chloroethyl acetate [9]. Similarly, the synthesis of acetals or ketals can be achieved in an alcoholic medium [10]. Although the oxidation of alkenes in such a medium is closely parallel to the Wacker process, the chemistry of these reactions is far beyond the scope of this section, which is limited to Wacker-type reactions in aqueous media, and will not be discussed here. [Pg.482]

Before any definite conclusions could be drawn concerning the rate-limiting step of the Wacker process, it was necessary to determine the actual isotope effects for the decomposition reaction. This was accomplished by competitive isotope effects nsing l,2-dideuteroethene. "" As shown in Scheme 5, the competitive isotope effect was approximately two. [Pg.479]

In principle, there can be many other Pd-catalyzed rearrangement reactions. At present, however, the overall scope of Pd-catalyzed rearrangement reactions is still rather limited. In one sense, lack of skeletal rearrangements in some Pd-catalyzed reactions, such as Wacker processes, where cationic species may be implicated as transient species, is considered to be a very desirable feature of organopalladium chemistry. On the other... [Pg.1245]

To the author s knowledge, there are at present no major industrial processes which could be strictly defined as nonacid catalysis that make use of zeolite-based catalysts. This is in contrast to acid catalysis where zeolites continue to make an impact. Technically, a number of zeolite-based catalysts for reactions, such as Wacker chemistry and olefin or diolefin oligomerization reactions, appear to be quite attractive, and it is almost certainly economic factors that have limited further development. [Pg.66]


See other pages where Wacker process limitations is mentioned: [Pg.78]    [Pg.78]    [Pg.20]    [Pg.198]    [Pg.30]    [Pg.13]    [Pg.1044]    [Pg.314]    [Pg.362]    [Pg.3]    [Pg.383]    [Pg.286]    [Pg.180]    [Pg.21]    [Pg.256]    [Pg.80]    [Pg.34]    [Pg.1365]    [Pg.126]    [Pg.19]    [Pg.135]    [Pg.5]    [Pg.292]    [Pg.1263]    [Pg.480]    [Pg.120]    [Pg.235]    [Pg.48]   
See also in sourсe #XX -- [ Pg.372 , Pg.403 ]




SEARCH



Limiting processes

Process limitations

Processing limitations

Processing process limitations

Wacker

Wacker process

© 2024 chempedia.info