Visible-light photoredox catalysis

Fust L, Narayanam JMR, Stephenson CRJ (2011) Total Synthesis of (-t)-Gliocladin C Enabled by Visible-Light Photoredox Catalysis. Angew Chem Int Ed 50 9655... [Pg.255]

Visible light photoredox catalysis with transition metal complexes and its synthetic appUcations 13CRV5322. [Pg.219]

Neumann M, Zeitler K (2012) Application of microllow conditions to visible light photoredox catalysis. Org Lett 14 2658-2661... [Pg.298]

Iqbak N, Choi S, Ko E, Cho EJ (2012) Trifluoromethylation of heterocycles via visible light photoredox catalysis. Tetrahedron Lett 53 2005-2008... [Pg.225]

Functionalization of C(sp )-H Bond by Visible-Light Photoredox Catalysis... [Pg.71]

Keywords Visible-light photoredox catalysis Sustainable chemistry C-C coupling... [Pg.71]

The Stephenson s work undoubtedly stimulates a rapid development of visible-light-driven C(sp )-H bond functionalization of tertiary amines. Soon afterward, numerous nucleophiles were employed under the principle of iminium ions chemistry by visible-light photoredox catalysis (Scheme 3.4). The oxidative Mannich reaction of Af-Aryl tetrahydroisoquinoUnes with ketones [17] and enol silanes [18] were developed by Rueping and Xia, respectively. As a follow-up work. Rueping et al. [19] reported an efiicient alkynylation of a-C(sp )-H bond... [Pg.73]

Scheme 3.5 Visible-light photoredox catalysis with gold complex [31]...

Aerobic photooxidation of epoxides to carbo grlic acids has been achieved in the presence of magnesium bromide. Visible light photoredox catalysis has been applied to the regioselective synthesis of a-brominated (di)ketones from electron-rich epoxides. ... [Pg.157]

Condie AG, Gonzalez-G6mez JC, Stephenson CRJ (2010) Visible-light photoredox catalysis Aza-Henry reactions via C—H functionalization. J Am Chem Soc 132 1464-1465... [Pg.102]

Xuan J, Xiao W-J (2012) Visible-light photoredox catalysis. Angew Chem Int Ed 51 6828-6838... [Pg.391]

Prier CK, Rankic DA, MacMillan DWC (2013) Visible light photoredox catalysis with transition metal complexes applications in organic synthesis. Chem Rev 113 5322-5363... [Pg.391]

Tucker JW, Nguyen JD, Narayanam JMR, Krabbe SW, Stephenson CRJ (2010) Tin-free radical cyclization reactions initiated by visible light photoredox catalysis. Chem Commun 46 4985 987... [Pg.392]

Kohls P, Jadhav D, Pandey G, Reiser O (2012) Visible light photoredox catalysis generation and addition of V-aryltetrahydroisoquinoline-derived a-amino radicals to Michael acceptors. Org Lett 14 672-675... [Pg.393]

Zhu S, Das A, Bui L, Zhou H, Curran DP, Rueping M (2013) Oxygen switch in visible-light photoredox catalysis radical additions and cyclizations and unexpected C-C-bond cleavage reactions. J Am Chem Soc 135 1823-1829... [Pg.393]

As a recent progress in the radical cyclization methodology, Liu applied visible-light photoredox catalysis (Scheme 43) [66] in the presence of /cc-Ir(ppy)3 complex as a potent photoredox catalyst, blue LED irradiation ( =450nm) to a mixture of a-bromo ester 95 and styrene derivative 96 resulted in clean formation of y-lactone 97. [Pg.272]

One of the most important routes to diverse 3,3-disubstituted oxindoles is the tandem radical cyclization of JV-arylacrylamides [39]. Visible-light photoredox catalysis has proved to be a powerful tool in providing reactive radical intermediates. The development of photocatalytic radical cyclizations ofJV-arylacrylamides... [Pg.422]

At the same time. Rueping and coworkers reported a similar functionalization of peptides and glycine esters through a combination of visible-light photoredox catalysis and Lewis acid catalysis (Eqs. (13.21) and (13.22)) [63]. The addition of the Lewis acid Zn(OAc)2 was essential for C-H arylation due to its capacity to activate the electrophilic imine intermediate. [Pg.431]

Scheme 13.29 Preparation of LY2784544 enabled by visible-light photoredox catalysis.

Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...