Viscosity non-Newtonian fluids

Newtonian Flow Fluid flow that obeys Newton s law of viscosity. Non-Newtonian fluids may exhibit Newtonian flow in certain shear rate or shear stress regimes. See also Newtonian Fluid. 

Non-Newtonian Fluids Die Swell and Melt Fracture. Eor many fluids the Newtonian constitutive relation involving only a single, constant viscosity is inappHcable. Either stress depends in a more complex way on strain, or variables other than the instantaneous rate of strain must be taken into account. Such fluids are known coUectively as non-Newtonian and are usually subdivided further on the basis of behavior in simple shear flow. 

Heat Exchangers Using Non-Newtonian Fluids. Most fluids used in the chemical, pharmaceutical, food, and biomedical industries can be classified as non-Newtonian, ie, the viscosity varies with shear rate at a given temperature. In contrast, Newtonian fluids such as water, air, and glycerin have constant viscosities at a given temperature. Examples of non-Newtonian fluids include molten polymer, aqueous polymer solutions, slurries, coal—water mixture, tomato ketchup, soup, mayonnaise, purees, suspension of small particles, blood, etc. Because non-Newtonian fluids ate nonlinear in nature, these ate seldom amenable to analysis by classical mathematical techniques. 

A significant heat-transfer enhancement can be obtained when a nonckcular tube is used together with a non-Newtonian fluid. This heat-transfer enhancement is attributed to both the secondary flow at the corner of the nonckcular tube (23,24) and to the temperature-dependent non-Newtonian viscosity (25). Using an aqueous solution of polyacrjiamide the laminar heat transfer can be increased by about 300% in a rectangular duct over the value of water (23). 

For non-Newtonian fluids the correlations in Figure 35 can be used with generally acceptable accuracy when the process fluid viscosity is replaced by the apparent viscosity. For non-Newtonian fluids having power law behavior, the apparent viscosity can be obtained from shear rate estimated by... 

Gla.ss Ca.pilla.ry Viscometers. The glass capillary viscometer is widely used to measure the viscosity of Newtonian fluids. The driving force is usually the hydrostatic head of the test Hquid. Kinematic viscosity is measured directly, and most of the viscometers are limited to low viscosity fluids, ca 0.4—16,000 mm /s. However, external pressure can be appHed to many glass viscometers to increase the range of measurement and enable the study of non-Newtonian behavior. Glass capillary viscometers are low shear stress instmments 1—15 Pa or 10—150 dyn/cm if operated by gravity only. The rate of shear can be as high as 20,000 based on a 200—800 s efflux time. 

A constant is often determined from measurements with a Newtonian oil, particularly when the caUbrations are suppHed by the manufacturer. This constant is vaUd only for Newtonian specimens if used with non-Newtonian fluids, it gives a viscosity based on an inaccurate shear rate. However, for relative measurements this value can be useful. Employment of an instmment constant can save a great deal of time and effort and increase accuracy because end and edge effects, sHppage, turbulent interferences, etc, are included. 

In most rotational viscometers the rate of shear varies with the distance from a wall or the axis of rotation. However, in a cone—plate viscometer the rate of shear across the conical gap is essentially constant because the linear velocity and the gap between the cone and the plate both increase with increasing distance from the axis. No tedious correction calculations are required for non-Newtonian fluids. The relevant equations for viscosity, shear stress, and shear rate at small angles a of Newtonian fluids are equations 29, 30, and 31, respectively, where M is the torque, R the radius of the cone, v the linear velocity, and rthe distance from the axis. 

Some concerns directly related to a tomizer operation include inadequate mixing of Hquid and gas, incomplete droplet evaporation, hydrodynamic instabiHty, formation of nonuniform sprays, uneven deposition of Hquid particles on soHd surfaces, and drifting of small droplets. Other possible problems include difficulty in achieving ignition, poor combustion efficiency, and incorrect rates of evaporation, chemical reaction, solidification, or deposition. Atomizers must also provide the desired spray angle and pattern, penetration, concentration, and particle size distribution. In certain appHcations, they must handle high viscosity or non-Newtonian fluids, or provide extremely fine sprays for rapid cooling. 

All fluids for which the viscosity varies with shear rate are non-Newtonian fluids. For uou-Newtouiau fluids the viscosity, defined as the ratio of shear stress to shear rate, is often called the apparent viscosity to emphasize the distiuc tiou from Newtonian behavior. Purely viscous, time-independent fluids, for which the apparent viscosity may be expressed as a function of shear rate, are called generalized Newtonian fluids. 

Non-Newtonian fluids include those for which a finite stress 1,. is reqjiired before continuous deformation occurs these are c ailed yield-stress materials. The Bingbam plastic fluid is the simplest yield-stress material its rheogram has a constant slope [L, called the infinite shear viscosity. 

The term aK2v", derived from reptation theory, describes the velocity-dependent energy necessary to fracture the bulk adhesive. K2 is the consistency which relates the viscosity to the shear rate for a non-newtonian fluid. a = TtraL fh", with r being the chain radius, L the chain length, a the density of chains crossing over the fracture plane, and h is the distance between the chain and reptation tube. 

The viscosity of a fluid arises from the internal friction of the fluid, and it manifests itself externally as the resistance of the fluid to flow. With respect to viscosity there are two broad classes of fluids Newtonian and non-Newtonian. Newtonian fluids have a constant viscosity regardless of strain rate. Low-molecular-weight pure liquids are examples of Newtonian fluids. Non-Newtonian fluids do not have a constant viscosity and will either thicken or thin when strain is applied. Polymers, colloidal suspensions, and emulsions are examples of non-Newtonian fluids [1]. To date, researchers have treated ionic liquids as Newtonian fluids, and no data indicating that there are non-Newtonian ionic liquids have so far been published. However, no research effort has yet been specifically directed towards investigation of potential non-Newtonian behavior in these systems. 

Non-Newtonian fluids vary significantly in their properties that control flow and pressure loss during flow from the properties of Newtonian fluids. The key factors influencing non-Newtonian fluids are their shear thinning or thickening characteristics and time dependency of viscosity on the stress in the fluid. 

Shear rate dependence of apparent viscosity for Newtonian and non-Newtonian fluids plotted on linear co-ordinates... 

As in the case of Newtonian fluids, one of the most important practical problems involving non-Newtonian fluids is the calculation of the pressure drop for flow in pipelines. The flow is much more likely to be streamline, or laminar, because non-Newtonian fluids usually have very much higher apparent viscosities than most simple Newtonian fluids. Furthermore, the difference in behaviour is much greater for laminar flow where viscosity plays such an important role than for turbulent flow. Attention will initially be focused on laminar-flow, with particular reference to the flow of power-law and Bingham-plastic fluids. 

For a Newtonian fluid, the data for pressure drop may be represented on a pipe friction chart as a friction factor = (R/pu2) expressed as a function of Reynolds number Re = (udp/n). The friction factor is independent of the rheological properties of the fluid, but the Reynolds number involves the viscosity which, for a non-Newtonian fluid, is... 

Figures 8.5 and 8.6. The liquid is carried round in the spaces between consecutive gear teeth and the outer casing of the pump, and the seal between the high and low pressure sides of the pump is formed as the gears come into mesh and the elements of fluid are squeezed out. Gear pumps are extensively used for both high-viscosity Newtonian liquids and non-Newtonian fluids. The lobe-pump (Figures 8.7 and 8.8) is similar, but the gear...

What is a non-Newtonian fluid Describe the principal types of behaviour exhibited by these fluids. The viscosity of a non-Newtonian fluid changes with the rate of shear according to the approximate relationship ... 

The effective viscosity of a non-Newtonian fluid can be expressed by the relationship ... 

Water, of viscosity 1 mN s/m2 flowing through the pipe at the same mean velocity gives rise to a pressure drop of I04 N/m2 compared with 105 N/m2 for the non-Newtonian fluid. What is the consistency ("k vaiuei of the non-Newtonian fluid ... 

Two liquids of equal densities, the one Newtonian and the other a non-Newtonian power law fluid, flow at equal volumetric rates down two wide vertical surfaces of the same widths. The non-Newtonian fluid has a power law index of 0.5 and has the same apparent viscosity as the Newtonian fluid when its shear rate is 0,01 s-1. Show that, for equal surface velocities of the two fluids, the film thickness for the non-Newtonian fluid is 1.125 times that of the Newtonian fluid. 

The Martinelli correlations for void fraction and pressure drop are used because of their simplicity and wide range of applicability. France and Stein (6 ) discuss the method by which the Martinelli gradient for two-phase flow can be incorporated into a choked flow model. Because the Martinelli equation balances frictional shear stresses cuid pressure drop, it is important to provide a good viscosity model, especially for high viscosity and non-Newtonian fluids. 

The measurements are carried out at preselected shear rates. The resulting curves are plotted in form of flow-curves t (D) or viscosity-curves ti (D) and give information about the viscosity of a substance at certain shear rates and their rheological character dividing the substances in Newtonian and Non-Newtonian fluids. 

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