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Virial expression for the bulk pressure

By an approadi similar to the one outlined in Section E.3.1.1, we may derive a molecular expression for the bulk pressure Py, following again the original [Pg.444]

By the same logic applied before to Eq. (E.31), it is a simple matter to show that [Pg.445]

when summed over a and because of Eq. (E.64) these terms may be combined leading to [Pg.446]

Together Eqs. (E.70), (E.73), and (E.74) constitute tlie virial expression for the bulk pressure, which parallels Eq. (5.63) for the stress exerted by a con-fined fluid on the planar substrates of a slit-pore. [Pg.446]


See other pages where Virial expression for the bulk pressure is mentioned: [Pg.444]    [Pg.444]    [Pg.444]    [Pg.444]    [Pg.324]    [Pg.109]    [Pg.86]    [Pg.96]    [Pg.2310]   


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