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Vibrational spectra dinitrogen complexes

Fig. 10. Section of the MO scheme of the dinitrogen complex I and optical absorption spectrum of I with assignments. Insert low-temperature spectrum of a KBr pellet showing vibrational structure of the LF transitions. Fig. 10. Section of the MO scheme of the dinitrogen complex I and optical absorption spectrum of I with assignments. Insert low-temperature spectrum of a KBr pellet showing vibrational structure of the LF transitions.
Replacement of the dinitrogen ligand in [Os(N2)(NH3)5] by pyridine under aerobic conditions or of the weakly bound triflate ligand in [0s(0S02CF3)(NH3)5] + by pyridine yields [Os(py)(NH3)j] cyclic voltammetric studies show reversible reduction to [Os(py)(NH3)5f" 62.90,91 and the surface-enhanced Raman spectrum (SERS) of the complex (both normal and deuteriated) shows Os-N, ammine and internal pyridine vibrational modes. Infrared spectra were also measured. ... [Pg.534]


See other pages where Vibrational spectra dinitrogen complexes is mentioned: [Pg.377]    [Pg.391]    [Pg.109]    [Pg.105]    [Pg.120]    [Pg.784]    [Pg.784]    [Pg.210]    [Pg.105]    [Pg.37]    [Pg.120]   
See also in sourсe #XX -- [ Pg.23 , Pg.28 , Pg.55 ]

See also in sourсe #XX -- [ Pg.23 , Pg.28 , Pg.55 ]

See also in sourсe #XX -- [ Pg.23 , Pg.28 , Pg.55 ]

See also in sourсe #XX -- [ Pg.23 , Pg.28 , Pg.55 ]




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