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Vertex inversion

D. A. Dixon and A. J. Arduengo III,/. Am. Chem. Soc., 109, 338 (1987). Periodic Trends in the Edge and Vertex Inversion Barriers for Tricoordinate Pnictogen Hydrides and Fluorides. [Pg.84]

Ab initio MO calculations, including contributions of the electron correlation by a second-order Moller-Plesset (MP2) perturbation approach, predict PH3 (Cg to invert by a vertex inversion process through a planar trigonal transition state (Dg, ) rather than by an edge inversion process through a planar, T-shaped transition state (Cgv) [1, 2] for a topological electron density analysis of tricoordinate phosphorus inversion processes, see [3]. [Pg.170]

Keywords Edge inversion Vertex inversion Transition state Recoupled pair bond Recoupled pair bond dyad Generalized valence bond (GVB) theory... [Pg.191]

See other pages where Vertex inversion is mentioned: [Pg.16]    [Pg.383]    [Pg.232]    [Pg.356]    [Pg.1672]    [Pg.1672]    [Pg.74]    [Pg.75]    [Pg.77]    [Pg.8]    [Pg.9]    [Pg.11]    [Pg.231]    [Pg.355]    [Pg.1671]    [Pg.1671]    [Pg.191]    [Pg.192]    [Pg.203]    [Pg.17]    [Pg.17]   
See also in sourсe #XX -- [ Pg.8 , Pg.9 , Pg.11 ]

See also in sourсe #XX -- [ Pg.8 , Pg.9 , Pg.11 ]



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