Vapor condensation temperature

FIG. 13-12 Liq iiid boiling points and vapor condensation temperatures for maximum-boiling azeotrope mixtures of chloroform and acetone at 101.3 kPa (1 atm) total pressure. 

A fouled condenser can be identified by an increase in vapor condensing temperature, whereas a fouled general cooler will not provide the anticipated hot water return temperature. Fouling is the primary factor in heat-transfer coefficient with which we are most concerned, and one which we can directly influence with a good water treatment program. 

The boiling point of liquid is frequently used to estimate the purity of the liquid. A similar approach is taken for solvents. Impurities cause the boiling point of solvents to increase but this increase is very small (in the order of O.OTC per 0.01% impurity). Considering that the error of boiling point can be large, contaminated solvents may be undetected by boiling point measurement. If purity is important it should be evaluated by some other, more sensitive methods. The difference between boiling point and vapor condensation temperature is usually more sensitive to admixtures. If this difference is more than 0.1°C, the presence of admixtures can be suspected. 

Having assisted desolvation in this way, the carrier gas then carries solvent vapor produced in the initial nebulization with more produced in the desolvation chamber. The relatively large amounts of solvent may be too much for the plasma flame, causing instability in its performance and, sometimes, putting out the flame completely. Therefore, the desolvation chamber usually contains a second section placed after the heating section. In this second part of the desolvation chamber, the carrier gas and entrained vapor are strongly cooled to temperatures of about 0 to -10 C. Much of the vapor condenses out onto the walls of the cooled section and is allowed to drain away. Since this drainage consists only of solvent and not analyte solution, it is normally directed to waste. 

Variable Air Flow Fans. Variable air flow fans are needed ia the process iadustry for steam or vapor condensing or other temperature critical duties. These also produce significant power saviags. Variable air flow is accompHshed by (/) variable speed motors (most commonly variable frequency drives (VFDs) (2) variable pitch fan hubs (J) two-speed motors (4) selectively turning off fans ia multiple fan iastaHations or (5) variable exit louvers or dampers. Of these methods, VFDs and variable pitch fans are the most efficient. Variable louvers, which throttle the airflow, are the least efficient. The various means of controlling air flow are summarized ia Table 3. 

The process operates at 1 kPa (10 mbars) and 450 kW of power. When the condenser temperature reaches 580°C, the power is reduced to 350 kW. Cooling water is appHed to the condenser, throughout distillation, by means of sprays. Normally distillation takes 10—12 hours and the end point is signified by an increase in furnace temperature and a decrease in vapor temperature to 500—520°C. At this point the power is turned off and the vacuum pump is shut down. Nitrogen is then bled into the system to prevent oxidation of 2inc. 

When sihca volatilizes, vapors condense on cooler areas to form a white bloom that can be removed by heat or dilute hydrofluoric acid. Because dilute hydrofluoric acid also attacks the substrate, a mild, careful treatment is required. To minimize volatilization, the temperature should be as low as possible. 

A solution of sulfur trioxide [7446-11-9] dissolved in chlorosulfonic acid [7990-94-5] CISO H, has been used as a smoke (U.S. designation FS) but it is not a U.S. standard agent (see Chlorosulfuric acid Sulfuric acid and sulfur trioxide). When FS is atomized in air, the sulfur trioxide evaporates from the small droplets and reacts with atmospheric moisture to form sulfuric acid vapor. This vapor condenses into minute droplets that form a dense white cloud. FS produces its effect almost instantaneously upon mechanical atomization into the atmosphere, except at very low temperatures. At such temperatures, the small amount of moisture normally present in the atmosphere, requires that FS be thermally generated with the addition of steam to be effective. FS can be used as a fill for artillery and mortar shells and bombs and can be effectively dispersed from low performance aircraft spray tanks. FS is both corrosive and toxic in the presence of moisture, which imposes limitations on its storage, handling, and use. 

Dilute (1—3%), chloride-containing solutions of either HOCl, hypochlorite, or aqueous base, can be stripped in a column against a current of CI2, steam, and air at 95—100°C and the vapors condensed giving virtually chloride-free HOCl solutions of higher concentration in yields as high as 90% (122—124). Distillation of more concentrated solutions requires reduced pressure, lower temperature, and shorter residence times to offset the increased decomposition rates. 

Evaporative crystalli rs generate supersaturation by removing solvent, thereby increasing solute concentration. These crystallizers may be operated under vacuum, and, ia such circumstances, it is necessary to have a vacuum pump or ejector as a part of the unit. If the boiling poiat elevation of the system is low (that is, the difference between the boiling poiat of a solution ia the crystallizer and the condensation temperature of pure solvent at the system pressure), mechanical recompression of the vapor obtained from solvent evaporation can be used to produce a heat source to drive the operation. 

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