Vanadium complexes dithiolates

Dithiolene complexes was the name suggested by McCleverty47 for complexes of unsaturated 1,2-dithiols without implying any particular ligand structure or valence formalism. The dithiolene complexes described differ from the vanadium(III) dithiolates (Section 33.4.6) reported by three independent groups.48... 

VO(Et2NCS2)2] has discrete molecules with five-coordinate square pyramids, with thf oxygen at the apex with d(V=0) = 1.59 A.667 The vanadium atom lies approximately 0.75 above the plane of the four sulfur atoms and the average V—S distance is 2.402 A, shorte than for most vanadium dithiolate complexes 667 IR, electronic and ESR spectra are consisten... 

Vanadium(III) complexes, 473 adenine, 475 alcohols, 478 amides, 474, 480 amines, 474 amino acids, 484 ammonia, 474 aqua, 477 arsines, 476 azide, 475 bipyridyl, 475 bromides, 483 carboxylates, 479 catecholates, 478 chlorides, 482 complexones, 485 cyanides, 474,476 (Wethyl sulfoxide, 480 dioxygen, 478 dithiocarbamates, 481 dithiolates, 481 dithiophosphinates, 481 ethers, 478... 

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