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Vanadium complexes, bond valence

A good example of a tetrahedral metal complex is VCU, the coordinate system for which is shown in Fig. 9-16. We have already discussed the role of s and f valence orbitals in a tetrahedral molecule (Chapter V). The 4s and 4p orbitals of vanadium can be used to form tr molecular orbitals. The 34, and orbitals are also situated properly for such use. In valence-bond language, jd and sp hybrid orbitals are both tetrahedrally directed. The and... [Pg.194]

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Valence Complexes

Vanadium complexes

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