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Valence shell electron pair repulsion trigonal pyramidal geometry

If an attempt were made to apply the rules of valence shell electron pair repulsion theory to radicals, it would not be clear how to treat the single electron. Obviously, a single electron should not be as large as a pair of electrons, but it is expected to result in some repulsion. Therefore, it is difficult to predict whether a radical carbon should be sp2 hybridized with trigonal planar geometry (with the odd electron in a p orbital), sp3 hybridized with tetrahedral geometry (with the odd electron in an sp3 AO), or somewhere in between. Experimental evidence is also somewhat uncertain. Studies of the geometry of simple alkyl radicals indicate that either they are planar or, if they are pyramidal, inversion is very rapid. [Pg.921]


See other pages where Valence shell electron pair repulsion trigonal pyramidal geometry is mentioned: [Pg.288]    [Pg.43]    [Pg.144]    [Pg.190]    [Pg.710]    [Pg.877]    [Pg.436]    [Pg.257]    [Pg.18]    [Pg.26]    [Pg.257]   
See also in sourсe #XX -- [ Pg.430 , Pg.431 , Pg.433 , Pg.437 ]




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