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Valence electrons molecular orbital mode

The PKS model has been criticized (27-29) for the assumption of a single frequency and its unsatisfactory description of the magnetic circular dichroism (MCD) found for the intervalence band of the Creutz-Taube ion (30). In a series of papers (31), Ondrechen and coworkers developed a more realistic three-site model for delocalized (class III) bridged mixed-valence complexes. This model incorporates many features of the PKS model but differs in that it explicitly includes the bridge, it uses a molecular orbital basis of one-electron functions, and the choice of important vibrational modes is not the same. The near-IR band line shape of the Creutz-Taube ion has been reasonably... [Pg.281]

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See also in sourсe #XX -- [ Pg.664 , Pg.665 , Pg.666 , Pg.782 ]



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Electron orbitals

Electron, orbiting

Electronic modes

Electrons, valence orbitals

Modes molecular

Orbital electrons

Valence electron

Valence electrons Valency

Valence orbital

Valence orbitals

Valency orbitals

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