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Two-Directional Glycosylation Strategies

Scheme4.25 The preparation ofthe Galili pentasaccharide using thioglycosyl donors and acceptors in a two-directional glycosyl-ation strategy. Scheme4.25 The preparation ofthe Galili pentasaccharide using thioglycosyl donors and acceptors in a two-directional glycosyl-ation strategy.
As each glycosylation reaction may produce two anomers, many studies are directing at the development of strategies to control the stereochemistry of glycosylation reactions. However, the latter topic is not the focus of this chapter, so only general principles of the stereochemistry of glycosylation reactions are discussed. [Pg.61]

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Direct glycosylation

Glycosylation strategy

Strategy directed

Two-direction glycosylation

Two-direction glycosylation strategy

Two-directional

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