Tungsten species

Another oxyanion of interest to soil chemists is that of tungsten, which is in itself important but is also important because it forms polymers and reacts with both molybdenum and phosphorus oxyanions to form mixed polymers. Because tungsten species are toxic, its oxyanionic species, including polymers, are of interest [28],... 

An important contribution that developed into the catalytic use of the vinylidene complexes for the construction of carbon frameworks was reported by two research groups independently for the preparation of Fischer-type carbene complexes by the reaction of terminal alkynes with pentacarbonylchromium or tungsten species in the presence of oxygen nucleophiles. 

A copper(O) complex, electro-generated from Cu(acac)2, is able to undergo an oxidative addition with benzyl and allyl bromides. Further reduction leads to the coupling products bibenzyl and 1,5-hexadienes Methyl-3-hexene-l,6-dicarb-oxylate can be prepared from butadiene and CO by electroreduction if di-Fe dicyclopentadienyl tetracarbonyl is used as redox catalyst Electro-generated low-valent tungsten species are able to reductively dimerize benzaldehyde to stilbene according to Eq. 83. The reduction potential was controlled at the third wave of the WClg catalyst (V = -1900 mV/SCE)... 

I WOfi octahedra. The nature of the tungsten species present depends not only on the... 

Transport properties (continued.) semiclassical model, 192-193 temperature-dependent resistivity of nanowires, 193-198 Triplet sites on supports, 63-64 Tungsten species, SiC>2-supported, 63 Turnover numbers (TON), nanostructured materials, 6... 

CpFe(CO)2 Na and after treatment with acid and decomplexation with sodium iodide in acetone the free alkene is isolated (Scheme 97). In addition, certain metal carbonyls like Co2(CO)g, Fe(CO)s and Mo(CO)e effectively deoxygenate epoxy-esters and -ketones. Also low-valent tungsten species and metallocenes may be used for the regeneration of alkenes. 

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