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Tungsten complexes silyls

Various alkylgermanes add across the Si-C double bond in the silylene complex 116 to yield germyl(silyl)tungsten complexes (Equation (201), Table 25).248... [Pg.758]

F. Hoffmann und G. Roewer reported on reactions of cyclohexasilylpotassium with transition metal compounds, and C. Marschner described a Cp-fiee hafnium silyl-substituted complex. A series of four papers from the group of W. Malisch deal with the description of silanol functionalities in organometallic iron and tungsten complexes and the synthesis of perchlorinated metallo siloxanes. [Pg.3]

Summary Thermal rearrangement of the short-lived phosphinidene complex [(OC)5W PCH(SiMe3)2 ] yielded stereoselectively an ri -f-phosphaalkene tungsten complex via 1,2-silyl shift this product was isolated and unambiguously characterized by multinuclear NMR spectroscopy. We also report preliminary studies on the reactivity of this T] - -phosphaalkene complex toward (Me2N)3P, cyclopentadiene and DMAD. [Pg.202]

Half-Sandwich Tungsten Complexes with Silyl-Functionalized r -Cyclopentadienyl Ligand ... [Pg.474]

TRICARBONYL-(ii5-CYCLOPENTADIENYL)SILYL COMPLEXES OF CHROMIUM, MOLYBDENUM, AND TUNGSTEN... [Pg.104]

See other pages where Tungsten complexes silyls is mentioned: [Pg.2062]    [Pg.2062]    [Pg.2064]    [Pg.184]    [Pg.1249]    [Pg.67]    [Pg.183]    [Pg.1249]    [Pg.67]    [Pg.1177]    [Pg.474]    [Pg.475]    [Pg.474]    [Pg.475]    [Pg.453]    [Pg.2062]    [Pg.2062]    [Pg.2064]    [Pg.377]    [Pg.523]    [Pg.279]    [Pg.152]    [Pg.2064]    [Pg.242]    [Pg.550]    [Pg.550]    [Pg.279]   


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Complexes silyls

Silyl complexes

Silyl complexes of chromium, molybdenum and tungsten

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