Tungsten carbonyl compounds hydrides

Heterometal alkoxide precursors, for ceramics, 12, 60-61 Heterometal chalcogenides, synthesis, 12, 62 Heterometal cubanes, as metal-organic precursor, 12, 39 Heterometallic alkenes, with platinum, 8, 639 Heterometallic alkynes, with platinum, models, 8, 650 Heterometallic clusters as heterogeneous catalyst precursors, 12, 767 in homogeneous catalysis, 12, 761 with Ni—M and Ni-C cr-bonded complexes, 8, 115 Heterometallic complexes with arene chromium carbonyls, 5, 259 bridged chromium isonitriles, 5, 274 with cyclopentadienyl hydride niobium moieties, 5, 72 with ruthenium—osmium, overview, 6, 1045—1116 with tungsten carbonyls, 5, 702 Heterometallic dimers, palladium complexes, 8, 210 Heterometallic iron-containing compounds cluster compounds, 6, 331 dinuclear compounds, 6, 319 overview, 6, 319-352... 

In the cases of tungsten and molybdenum, the complexes are believed to be intermediates in the oxidation of alcohols to carbonyl compounds (a hydride abstraction reaction).85 Figure 2.28 illustrates some of the oxygen transfer... 

Fujiwara, Y., Ishikawa, R., Akiyama, F., Teranishi, S. Reductive coupling of carbonyl compounds to olefins by tungsten hexachloride-lithium aluminum hydride and some tungsten and molybdenum carbonyls. J. Org. Chem. 1978,43, 2477-2480. 

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