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Tropine Unsaturated acids

When hydrochloric acid or hydrobromic acid is the hydrolytic agent the replacement of the alcoholic hydroxyl of tropine respectively by chlorine or bromine has been observed to occur (186), while sulfuric acid causes dehydration to the unsaturated base, tropidine (192a). [Pg.275]

Structure XII was favored by Merling, for like Fischer s triacetonealka-mine, XIV (the mandelic ester possesses mydriatic properties (86)), the hydroxyl is gamma with respect to the nitrogen. Tropidine would then have an unsaturated iSmns-bridge while tropinic acid would be iV-methyl-... [Pg.280]

See other pages where Tropine Unsaturated acids is mentioned: [Pg.77]    [Pg.182]    [Pg.463]    [Pg.89]    [Pg.278]    [Pg.279]    [Pg.282]    [Pg.285]    [Pg.152]    [Pg.469]   
See also in sourсe #XX -- [ Pg.115 ]



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Acids, unsaturated

Tropin

Tropine

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