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Tris 2-Picolinyl Methane

The checkers prepared 2-bromo-6-picoline from inexpensive 2-amino-6-picoline R. Adams and S. Miyano, J. Am. Chem. Soc. 76, 3168-3171 (1954). [Pg.75]

The ligand HL is air stable. HL reacts with methanol solution of CuBr2 in air to afford HOL, bis(2-picolinyl)ketone (bpk), and MeOL.7a With catalytic amount of CuBr2, the bridgehead oxidation is quantitative. Under anaerobic conditions, HL and CuBr2 react to give CuBr2(HL) quantitatively. [Pg.76]

COPPER (TRIS(2-PICOLINYL)METHANE)ACETONITRILE HEXAFLUOROPHOSPHATE [Pg.76]

The checkers evaporated the CHC13 extracts to dryness, dissolved the crude product in a minimum of CHCI3, and precipitated the product by the addition of hexane. [Pg.76]

The copper complex is insoluble in nonpolar solvents but soluble in dichloro-methane, MeCN, and some organic solvents. The Cu(I) complex is air stable. [Pg.77]

C. COPPER (TRIS(2-PICOLINYL)METHANE)ACETONITRILE HEXAFLUOROPHOSPHATE... [Pg.76]

See other pages where Tris 2-Picolinyl Methane is mentioned: [Pg.74]    [Pg.74]    [Pg.75]    [Pg.75]    [Pg.76]    [Pg.76]    [Pg.77]    [Pg.74]    [Pg.74]    [Pg.75]    [Pg.75]    [Pg.76]    [Pg.76]    [Pg.77]   


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