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Triruthenium cyclopentadienyl clusters

NLO properties, 12, 128 organometallic complexes, 3, 318 as reaction materials, 3, 368 and selenium nucleophiles, 9, 471 surface chemistry on oxides, 12, 502 in triruthenium cyclopentadienyl clusters, 6, 799 trivalent halides, with metal carbonyl monoanions, 3, 347 Group 14 elements... [Pg.114]

Triruthenium Cyclopentadienyl Clusters Containing Group 13 Elements 799... [Pg.797]

Triruthenium Cyclopentadienyl Clusters Containing Hydrocarbyl Groups 800... [Pg.797]

As for the complexes which have never been observed for the triruthenium carbonyl clusters, several types of the hydrocarbyl ligands have been originally reported for the triruthenium complexes bearing cyclopentadienyl ligands tris(/r-alkylidene), s-ds-fii-rf -diene," nido-fii-jf 7/ -ruthenacyclopentadiene, and nyrf -ruthenabenzene ... [Pg.801]

Seven publications centre on the chemistry of triruthenium cyclopentadienyl complexes. Reaction of [Cp Ru(p -Cl)]4 with Li2S yields [Cp 3Ru3(p -Cl)(p -S)], however with a mixture of Li2S/NaSPri the related thiolate-capped cluster [(2p 3Ru3(p -SPr )(p -S)] results . Somewhat related is [Cp 3Ru3(S4)] which reacts with a variety of electrophiles (R" ) to afford thiolate-... [Pg.200]

Many types of hydrocarbyi ligands are known for the triruthenium clusters containing a cyclopentadienyl ligand /it3-alkylidyne, /it-alkylidene, /tj-j/ -vinylidene, /t3-J7 ( )-alkyne, ... [Pg.800]

Triangulated dodecahedral triruthenium cluster, [(Cp"Ru)3Ps] (72, Cp" = l,3-Bu2C5H3), with cyclopentadienyl and P5 ligands, has been obtained as a side-product (17%) in the co-thermolysis of [Cp Felt/ -Ps)] and Cp"Ru(CO>2 2 70 (Equation (24)). The reaction is less selective and several other products including hetero-trimetallic and tetrametallic iron-ruthenium clusters are formed. [Pg.810]

See other pages where Triruthenium cyclopentadienyl clusters is mentioned: [Pg.122]    [Pg.123]    [Pg.141]    [Pg.143]    [Pg.797]    [Pg.817]    [Pg.122]    [Pg.123]    [Pg.141]    [Pg.143]    [Pg.797]    [Pg.817]    [Pg.797]    [Pg.798]    [Pg.853]    [Pg.73]    [Pg.46]    [Pg.46]    [Pg.169]    [Pg.801]    [Pg.812]    [Pg.812]    [Pg.845]    [Pg.202]   


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Triruthenium

Triruthenium cluster

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