Triphenylphosphine triphenylphosphorus

Beilstein Handbook Reference) BRN 0610776 CCRIS 4889 EINECS 210-036-0 HSDB 4266 NSC 10 NSC 215203 Phosphine, triphenyl- PP 360 Trifenyltosfin Triphenylphosphane Triphenylphosphide Triphenylphosphine Triphenylphosphorus. Used in organic synthesis, in the manufacture of phosphonium salts and other phosphorus compounds, as a polymerization initiator. White solid mpn 81° bp > 360° d 1.194 insoluble in H2O, soluble in organic solvents. BASF Corp. Elf Atochem N. Am. Janssen Chimica Morton Intn I. 

PiCoCmHu, Cobalt, (ti -cyclopentadienyl)-bis(triphenylphosphine)-, 26 191 P2Co207PtC33H24, Cobalt, heptacarbonyl-[l,2-ethanediylbis(diphenylphos-phine)]platinumdi-, 26 370 P2CrF3NO,C45Hii, Chromate(l -), hydri-donona-carbonyliron-p.-nitrido-bis(triphenylphosphorus)-(l +), 26 338... 

Oxidative deselenizations have also been described. For example, reaction of triphenylphosphorus selenide 181 with perfluorooxaziridine 80 resulted in complete deselenization affording triphenylphosphine oxide 182 in 97% yield <1997JOC6401>. 

P H, Re2C72H o, Rhenium(IV), octahydrido-tetrakis(triphenylphosphine)di-, 27 16 P4N20,2PtRh4C uH Rhodate(2-), dodeca-carbonylplatinumtetra-, bis[p.-nitrido-bis(triphenylphosphine)(l +)], 26 375 P4N20 4PtRh4Ci iH Rhodate(2-), tetra-decacarbonylplatinumtetra-, bis[p.-nitrido-bis(triphenylphosphorus)(l +)], 26 373... 

Bis(triphenylphosphine)iminium chloride [PPN]C1, which is easily synthesized3 or available commercially (Alfa Products, Danvers, Massachusetts the systematic IUPAC name for this salt is /u-nitrido-bis(triphenylphosphorus)(l+), is purified by dissolution in hot water, addition of activated charcoal, filtration of the solution, and crystallization from the cooling solution. The resulting crystalline [PPN] Cl is filtered and dried under high vacuum overnight. 

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