Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Triphenylmethyl peroxide rearrangement

An example of the rearrangement reaction is afforded by the decomposition of triphenylmethyl peroxide.11 89... [Pg.57]

Triphenylmethyl peroxide, 300 rearrangement, 336 Triphenylmethyl radical, 43, 300 dimer, 44, 301, 311 shape,311... [Pg.214]

Aromatic-aliphatic azo compounds can without exception be prepared by oxidation of the corresponding JV-alkyl-A -arylhydrazines. The oxidant must be one that reacts in neutral or alkaline conditions since the azo product rearranges to arylhydrazone in an acid medium. Mercury(n) oxide, introduced by Emil Fischer341 as oxidant, is almost always used for this reaction. 30% Hydrogen peroxide in hydrogen carbonate solution has been applied to dehydrogenation of A-aryl-A -(triphenylmethyl)hydrazines with good results.342... [Pg.592]

See other pages where Triphenylmethyl peroxide rearrangement is mentioned: [Pg.362]    [Pg.1238]   
See also in sourсe #XX -- [ Pg.336 ]

See also in sourсe #XX -- [ Pg.336 ]



SEARCH



Peroxides rearrangement

Triphenylmethyl

Triphenylmethyl peroxide

Triphenylmethylation

© 2024 chempedia.info