Trinitrobenzoyl azide

Trinitrobenzoyl azide (VIII) was prepared by Vasilevskii. Blokhshtein and Kustria [158] by the action of sodium azide on trinitrobenzoyl chloride... 

Trinitrobenzoyl Azide, (02N)3CeHa.C0iN3 mw 282.13, N 29.79% col cryst(from methyl acet), mp 92-6°(dec)(Ref 2) to 98°(dec)(Ref 3), expl at higher temps d 1.673 at 20°(Ref 2) sol in acet or aromatic hydrocarbons insol in aliphatic hydro-carbons(Ref 3) can be prepd by adding aq Na azide soln in methyl acet to a stirred soln of 2,4,6-trinitrobenzoyl chloride in methyl acet at -5 to 0° (higher temps must be avoided)(Ref 2). This compd decomposes at RT and especially rapidly in soln... 

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See also in sourсe #XX -- [ ]

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