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Trigonal prismatic metal clusters, valence

Despite the existence of 86-electron octahedral carbide clusters, such as Ru6(CO)i7C, the dianion [Rhf,(CO) uG]2 has 90 valence electrons and a trigonal prismatic array of metal atoms (structure XVIII in Fig. 8) (7). This fact could indicate that the three M—M bonds formally lost in the... [Pg.298]

See other pages where Trigonal prismatic metal clusters, valence is mentioned: [Pg.243]    [Pg.30]    [Pg.1489]    [Pg.36]    [Pg.50]    [Pg.1488]    [Pg.905]    [Pg.1040]    [Pg.234]    [Pg.149]    [Pg.238]    [Pg.277]    [Pg.223]   


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Metal valence

Prismatic

Trigonal-prismatic

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