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Trifluorosilyl radical

E. Synthesis of Bis(trifluorosilyl)mercury by Cocondensation OF Mercury and Trifluorosilyl Radicals... [Pg.207]

Hexafluorodisilane breaks down in a radioffequency glow-discharge to give trifluorosilyl radicals that react with a variety of metal atoms when co-condensed on a cold surface (equation 43). This method allows the synthesis of a range of homoleptic SiFs metal derivatives (see Homoleptic Compound) ... [Pg.4434]

The radicals, such as methyl, trifluoromethyl, and trifluorosilyl, used in this work have been found to oxidize zero-valent metals to their highest oxidation-state upon cocondensation with these metals on a cold surface at - 196°C. [Pg.204]

Another procedure for the preparation of very active zinc uses the metal atom approach in which zinc-metal vapor is coprecipitated with an ethereal solvent. The unstable bis(trifluorosilyl)zinc and bis(trifluoromethyl)zinc have been prepared by cocondensing Zn atoms with -SiFs radicals see Radicals) and -CFs radicals, respectively (generated by low-temperature radio-frequency glow discharge or plasma of hexafluoroethane or hexafluorodisilane). ... [Pg.5202]

See other pages where Trifluorosilyl radical is mentioned: [Pg.178]    [Pg.206]    [Pg.178]    [Pg.206]    [Pg.178]    [Pg.206]    [Pg.178]    [Pg.206]    [Pg.543]    [Pg.169]    [Pg.22]    [Pg.542]   
See also in sourсe #XX -- [ Pg.206 ]

See also in sourсe #XX -- [ Pg.23 , Pg.206 ]

See also in sourсe #XX -- [ Pg.206 ]



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