Triazolate complexes silver

The dicationic ditriflate salt of 1,2,4-trimethyltriazolium with silver acetate gives the bis-carbene complex 185 (00JOM(600)l 12). In excess silver acetate, the one-dimensional polymeric species with alternating silver ions and 1,2,4-triazol-3,5-diylidene carbenes result, where both carbon atoms of each heteroring are engaged in coordination. 

Involvement of two nucleophilic nitrogen atoms is thus typical for the amino heterocycles. The mutual disposition of the pyridine and amine nitrogen atoms allows the formation of chelate structures for the cobalt complexes of purine, 221 and 222. Structures with the N, iV -five-membered metal cycles were proven for the tri- and tetranuclear complexes of silver ) with 8-aminoquinoline (223) (92IC4370), and polymeric copper- and rhodium-acetate clusters (224). Another coordination mode can be found in the complexes of 4-amino-3,5-bis(pyridin-2-yl)-l,2,4-triazole, (225 or... 

SERS data for glycine adsorbed on silver colloidal particles include a band at 238 cm-1 due to vAg-N.403 vAgN modes were assigned from the IR spectra of [bis(l,2,4-triazol-l-yl)methane]silver(I) complexes AgX tz2(CH2) ER3 MeCN, where X = N03, R = Ph, E = P, As, Sb, and related systems.404... 

Sakano T, Okano M, Osakada K. Preparation of triazole-fumished ferrocene derivatives and their polymer complexes of silver(I). J Inorg Organomet Polym Mater 2009 19(1) 35 5. 

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