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Triangular metal clusters

Condensation of discrete triangular metal cluster units in the metal cluster plane is another way of building extended solid-state com-... [Pg.80]

Triangular metal cluster in which co-ordination about Fe and Pt is octahedral and square planar, respectively. The short Pt—Pt... [Pg.424]

Some Examples of Triangular Metal Cluster Compounds... [Pg.306]

Many non-carbonyl ligands such as NO, S, PR, O or RC can be edge or face-bridging ligands in triangular metal clusters (Fig. 2.12). Phosphines PR3 are typical donor terminal ligands in trinuclear triangular clusters. [Pg.68]

Fig. 2.13. Examples of structures of triangular metal clusters containing main-group bridging ligands... Fig. 2.13. Examples of structures of triangular metal clusters containing main-group bridging ligands...
The Iron Triad.—Mild protonation of the anion [Fe4(CO)u(/t-CO)(/e3-COMe)] yields [Fe4H(CO)i2(i -COMe)], which in turn reacts with strong acid to generate methane from the iy -COMe liquid X-ray crystal structures are reported for both iron complexes. Methods for the s mthesis of triangular metal-cluster complexes containing iUg-alkylidyne ligands have been reported and structures of this tsrpe have been established by X-ray diffraction methods for... [Pg.241]


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See also in sourсe #XX -- [ Pg.824 , Pg.825 , Pg.923 , Pg.924 ]

See also in sourсe #XX -- [ Pg.906 , Pg.907 , Pg.959 ]

See also in sourсe #XX -- [ Pg.68 ]




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