Triacetone amine

Primary amines form Schiff bases, (CH3 )2C=NR. Ammonia induces an aldol condensation followed by 1,4-addition of ammonia to produce diacetone amine (from mesityl oxide), 4-amino-4-methyl-2-pentanone [625-04-7] (CH2)2C(NH2)CH2COCH2, and triacetone amine (from phorone),... 

Tri (rt-butyl)phosphate (TBP), 79 674 Tri-l,10-phenanthroline-iron(II), 7 589 1-Triacontanol physical properties of, 2 3t cis-21-Triacontenoic acid physical properties, 5 32t Triacetate chiral stationary phase, 6 88t Triacetate fibers, 24 614 Triacetone amine... 

SCHEME 17.8 Reaction mechanism of triacetone amine from acetone and ammonia. 

A Selective Process to Prepare Triacetone Amine Young-Chan Son, Steven L. Suib, and Russell E. Malz, Jr. 

Another route to triacetone amine that involves the conversion of acetone and ammonia to acetonine [5] (2,2,4,4,6-pentamethyl-l,2,5,6-tetrahydro-pyrimidine) is made from acetone, ammonia and a catalyst at room temperature 16). After purification, acetonine is mixed with more than six equivalents of ace-... 

A number of aliphatic azotoxides [84], the structural formulas of which are cited below, have also been synthesized from triacetone-amine I ... 

As has been shown [85], the radical II is a substantially better antioxidant, inhibiting the oxidation of polypropylene, than is triacetone-amine (Fig. 30). This effect, as we believe, is related to the fact that triacetoneamine reacts with the radicals RO according to the scheme... 

Group of Dr. E.Sh. Kagan. A number of original electrosyntheses in a series of triacetone amine, piperidines, etc. [94,132-135] (see also synthesis of y-truxillic acid in collaboration with TomUov, Sect. 9.1.1). This group continues now to actively work in the field of organic electrosynthesis. 

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