Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Transverse plane

Because both spins are in the transverse plane and transition energy levels are matched, energy can be transferred from the protons to the nuclei. In this manner the rate of repolarization is controlled by rather than by Because the protons can interchange energy by spin-diffusion only a single-proton exists and its value is usually on the order of 1 s. As a result the preparation delay can be reduced from 10 s to about 5 s increasing the number of transients, which can be acquired by two or more orders of magnitude. [Pg.409]

Fig. 7. Diagiaimnatic lepiesentation of tfie ultiastmctuie of fiber wail components, where L = longitudinal, R = radial, and T = transverse plane of fiber. Fig. 7. Diagiaimnatic lepiesentation of tfie ultiastmctuie of fiber wail components, where L = longitudinal, R = radial, and T = transverse plane of fiber.
Moreover, precession under selective irradiation occurs in the longitudinal plane of the rotating frame, instead of rotation in the transverse plane, which occurs during the evolution of the FID. The magnitude of the vector undergoing precession about the axis of irradiation decreases due to relaxation and field inhomogeneity effects. [Pg.188]

Exploitation of the TROSY effect is rather straightforward. In contrast to 15N-HSQC (Heteronuclear Single Quantum Coherence) or standard triple-resonance experiments based on 15N-HSQC, no radio frequency pulses or composite pulse decoupling should be applied on amide protons when HN spin is not in the transverse plane. Likewise the 15N decoupling should be... [Pg.249]

One of the possibilities is to replace the evolution of the single-quantum states by the multiple-quantum ones during extended evolution periods. As theoretically predicted by Griffey and Redfield [34] and experimentally demonstrated by Grzesiek and Bax [35], keeping a spin pair in the state of multiple-quantum coherence (MQ) eliminates most of the dipolar contribution to the spin-spin relaxation. With the X-H (X is a heteronucleus) spin pairs, this is partially offset by a higher rate of proton cross-relaxation in the transverse plane with the remote H spins. Since the MQ coherences consist of transverse... [Pg.127]

K. A. Sikaris, K. R. Thulbom, and W. H. Sawyer, Resolution of partition coefficients in the transverse plane of the lipid bilayer, Chem. Phys. Lipids 29, 23-36 (1981). [Pg.268]

The 2D MMl structures are multimode waveguides in both the transverse directions. The modal interference along the propagation causes self and multiple images in the whole transverse plane. Thus, to have Nx x Ny images we need to have... [Pg.282]

Figure 10.3 The magnetic field generated by an RF pulse applies a torque to the bulk magnetization vector and drives it towards the transverse plane. Figure 10.3 The magnetic field generated by an RF pulse applies a torque to the bulk magnetization vector and drives it towards the transverse plane.
The following scalar magnetic flux gives transverse plane waves for A and S... [Pg.174]


See other pages where Transverse plane is mentioned: [Pg.2488]    [Pg.2489]    [Pg.409]    [Pg.259]    [Pg.18]    [Pg.289]    [Pg.359]    [Pg.213]    [Pg.7]    [Pg.30]    [Pg.38]    [Pg.422]    [Pg.37]    [Pg.215]    [Pg.216]    [Pg.354]    [Pg.229]    [Pg.454]    [Pg.254]    [Pg.254]    [Pg.268]    [Pg.269]    [Pg.271]    [Pg.275]    [Pg.244]    [Pg.274]    [Pg.49]    [Pg.308]    [Pg.308]    [Pg.309]    [Pg.310]    [Pg.9]    [Pg.37]    [Pg.273]    [Pg.639]    [Pg.642]    [Pg.9]    [Pg.131]    [Pg.133]    [Pg.133]    [Pg.168]   
See also in sourсe #XX -- [ Pg.15 ]

See also in sourсe #XX -- [ Pg.12 ]




SEARCH



Transverse relaxation loss of magnetisation in the x-y plane

© 2024 chempedia.info