Translational velocity, vibrational analysis

Conventional FTIR instruments, in which the interferometer mirror is translated at a constant velocity, are ideally suited to the analysis of steady state infrared emission. However, time resolution of the infrared emission is required in many applications, such as the measurement of absolute rate constants for the formation or subsequent relaxation of a vibrationally excited species. It is then necessary to follow the intensity of the emission (at a particular wavenumber if state-specific rate constants are required) as a function of time. For continuous-wave experiments, crude time resolution... 

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