Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Translational partition function and quantum mechanics

Let us consider a gas molecule with mass m free to displace in a container with the volume A/v/available for the displacement of the molecule. LetXi, X2 andXs be the length, width and height of the container  [Pg.153]

Quantum mechanics is used to calculate the energy levels of a molecule with mass /w in a recipient with lengthX], i.e.  [Pg.154]

With the translational energies being very narrow in a typical laboratory container, we can replace the equation with an integral and write the contribution according to Ox] in the form  [Pg.154]

By disregarding 1 with regard to n, through which we can change the variable u =n Pe, we obtain  [Pg.154]

The complete translational partition function for the three directions will therefore be  [Pg.155]


See other pages where Translational partition function and quantum mechanics is mentioned: [Pg.153]   


SEARCH



Partition function translation

Partition function translational

Partition translation

Partitioning mechanisms

Partitioning partition functions

Quantum partition function

Translation and

Translation mechanisms

© 2024 chempedia.info