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Transition-State Theory for Reactions on Surfaces

The activation energies can be established nnder the experimental conditions for which eq. (10.35) is valid. [Pg.263]

These two examples reveal that, within the same mechanism, the observed activation energy is strongly dependent npon the experimental conditions of surface coverage. [Pg.263]

4 Reaction between a molecule in the gas phase and an adsorbed molecule [Pg.263]

When the reaction follows the Rideal-Eley mechanism, where reactant A is in the gas phase and B is adsorbed, the rate is given by [Pg.263]

4 TRANSITION-STATE THEORY FOR REACTIONS ON SURFACES 10.4.1 Unimolecular reactions [Pg.263]

See other pages where Transition-State Theory for Reactions on Surfaces is mentioned: [Pg.263]    [Pg.265]    [Pg.267]   


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