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Polyhydride transition-metal complexes

Bayse, C.A. and Hall, M.B. (1999) Prediction of the Geometries of Simple Transition Metal Polyhydride Complexes hy Symmetry Analysis. Journal of the American Chemical Society, 121, 1348-1358. [Pg.232]

Generation of Reactive Intermediates via Photolysis of Transition-Metal Polyhydride Complexes... [Pg.343]

The photochemical properties of several transition metal polyhydride complexes are described. Irradiation of [MoH Cdppe) ] (dppe =... [Pg.343]

Transition metal polyhydride complexes attracted our attention for their easiness to liberate H2 giving coordinatively unsaturated species under mild conditions.3 The resulting intermediates are highly reactive and interact with various substrates to produce new complexes. In many cases, polyhydride complexes are fluxional, where the hydrogen atoms in the coordination sphere rapidly exchange their positions. [Pg.395]

Transition metal polyhydride complexes are remarkable for a number of reasons. Most of them are related to the peculiar chemical properties of the metal-hydride combination. There are, however, some specific phenomena in... [Pg.419]

Quantum exchange coupling in transition-metal polyhydride complexes. [Pg.437]

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