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Transition metal polyacrylates thermolysis

The pyrolysis of transition metal carboxylates (in the example of Ni " ) has an essential place due to both (a) the quantitative characteristics of the main stages and (b) the properties of the products obtained. Such metallopolymers can be prepared by two principally different routes by the above-mentioned polymer-analogous reactions, namely, by the interaction of polyacryhc acid with metal salts Ni, (PAA-Ni ), Co " ", Fe " ", and so on (method A), or by radical polymerization of the appropriated monomers—for example, nickel acrylate, [Ni(CH2CHCOO)2] , to give nickel polyacrylate (NiPAcr) (method C). The kinetic peculiarities of metallopolymers thermolysis were compared with the behavior of their low-molecular-weight analogues nickel propionate. [Pg.79]

See other pages where Transition metal polyacrylates thermolysis is mentioned: [Pg.79]    [Pg.79]    [Pg.81]    [Pg.83]    [Pg.85]    [Pg.87]   
See also in sourсe #XX -- [ Pg.79 , Pg.80 , Pg.81 , Pg.82 , Pg.83 , Pg.84 , Pg.85 , Pg.86 , Pg.87 ]



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