Transition metal organometallic synthesis

Allan J. Canty, Thomas Rodemann, and John H. Ryan, Transition Metal Organometallic Synthesis Utilising Diorganoiodine(HI) Reagents. . . Al-Ahmad, Saleem, see Ashe, Arthur J., HI... 

H. Alper, ed.. Transition Metal Organometallics in Organic Synthesis, Academic Press, Inc., New York, 1976. 

K. M. Nicholas, M. O. Nestle u. D. SEYFERTin II. Alper, Transition Metall Organometallics in Organic Synthesis, Vol. 2, Academic Press. New York 1978. 

For a monograph that discusses most of the reactions in this section, see Stowell, J.C. Carbanions in Organic Synthesis Wiley NY, 1979. For a review, see Noyori, R. in Alper Transition Metal Organometallics, in Organic Synthesis, vol. 1 Academic Press NY,... 

McQuillin, F. J., Parker, D. G., Stephenson, G. R., Transition Metal Organometallics for Organic Synthesis. Cambridge Press, 1991 Crabtree, R. H The Organometallic Chemistry of Transition Metals, 2nd ed. John Wiley Sons, New York, 1994. 

Broene RD (1995) In Hegedus LS (ed) Transition metal organometallics in organic synthesis. Comprehensive organometallic chemistry II, vol 12. Pergamon, Tarry-... 

Jaouen, G. In Transition Metal Organometallics in Organic Synthesis Alper, H., Ed. Academic Press New York, 1978 Vol. II, Chapter 2. 

F. J. McQuillin, Transition Metals Organometallics for Organic Synthesis, Cambridge University Press, Cambridge, 1991. 

Since the discovery of ferrocene in 1951 transition metal organometallic chemistry U has received much attention in numerous laboratories throughout the world. Compounds with a variety of unusual structures and properties have been prepared. Some of these compounds are of practical interest as catalysts for the synthesis of unusual and useful organic compounds 2>. 

The transition metal catalyzed synthesis of arylamines by the reaction of aryl halides or tri-flates with primary or secondary amines has become a valuable synthetic tool for many applications. This process forms monoalkyl or dialkyl anilines, mixed diarylamines or mixed triarylamines, as well as N-arylimines, carbamates, hydrazones, amides, and tosylamides. The mechanism of the process involves several new organometallic reactions. For example, the C-N bond is formed by reductive elimination of amine, and the metal amido complexes that undergo reductive elimination are formed in the catalytic cycle in some cases by N-H activation. Side products are formed by / -hydrogen elimination from amides, examples of which have recently been observed directly. An overview that covers the development of synthetic methods to form arylamines by this palladium-catalyzed chemistry is presented. In addition to the synthetic information, a description of the pertinent mechanistic data on the overall catalytic cycle, on each elementary reaction that comprises the catalytic cycle, and on competing side reactions is presented. The review covers manuscripts that appeared in press before June 1, 2001. This chapter is based on a review covering the literature up to September 1, 1999. However, roughly one-hundred papers on this topic have appeared since that time, requiring an updated review. 

McQuillin FJ, Parker DG, Stephenson G R (1991) Transition metal organometallics for organic synthesis. Cambridge University Press, New York... 

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