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Transition metal complexes octahedral binding modes

The versatile binding modes of the Cu2+ ion with coordination number from four to six due to Jahn-Teller distortion is one of the important reasons for the diverse structures of the Cu-Ln amino acid complexes. In contrast, other transition metal ions prefer the octahedral mode. For the divalent ions Co2+, Ni2+, and Zn2+, only two distinct structures were observed one is a heptanuclear octahedral [LnM6] cluster compound, and the other is also heptanuclear but with a trigonal-prismatic structure. [Pg.207]


See other pages where Transition metal complexes octahedral binding modes is mentioned: [Pg.479]    [Pg.365]    [Pg.1125]    [Pg.2705]    [Pg.650]    [Pg.2704]    [Pg.185]    [Pg.93]    [Pg.532]    [Pg.1178]   
See also in sourсe #XX -- [ Pg.411 , Pg.421 , Pg.422 ]




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