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Transition metal bonding Lewis-like structures

Following the obvious parallels with p-block hybridization and bonding, the formation of a duodectet-rule-conforming Lewis-like structural formula for an idealized ML transition-metal complex5 can be pictured as occurring in several steps. [Pg.367]

LEWIS-LIKE STRUCTURES IN TRANSITION METAL BONDING... [Pg.86]

Lewis-Like Structures in Transition Metal Bonding 87 ----------f/0 4,16---------------------------------... [Pg.87]

As a simple illustration of transition metal hybridization and Lewis-like structures, let us consider tungsten hexahydride (WHg) as a prototype of idealized sd hybridized bonding. The input file and chosen atomic numbering for the optimized (B3LYP/LANL2DZ-level) geometry of WHs are given in FO-4.16. [Pg.87]

The remarkable Lewis-like bonding of transition metals (see V B, pp. 365-387) is based on the primacy of sd hybridization and the associated 12-electron ( duodectet rule ) modification of Lewis structure diagrams. The idealized bond angles cDy between sd hybrid h, and sd - hybrid h, are found to satisfy an equation analogous to the Coulson orthogonality theorem (4.9) for the geometric mean hybridization parameter jx = namely,... [Pg.86]


See other pages where Transition metal bonding Lewis-like structures is mentioned: [Pg.364]    [Pg.429]    [Pg.451]    [Pg.88]    [Pg.83]    [Pg.288]    [Pg.419]    [Pg.555]    [Pg.15]    [Pg.246]    [Pg.680]    [Pg.4]    [Pg.11]    [Pg.124]    [Pg.160]    [Pg.39]    [Pg.5553]    [Pg.102]    [Pg.204]    [Pg.4]    [Pg.567]    [Pg.5]    [Pg.182]    [Pg.59]    [Pg.320]   
See also in sourсe #XX -- [ Pg.365 , Pg.366 , Pg.367 , Pg.368 , Pg.369 , Pg.370 , Pg.371 ]




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Lewis transition metal

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