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Transition longest-wavelength, alternant

Transition. See also Electronic transition 0-0, 37, 261-62 allowed and forbidden, 27 charge-transfer, 123-26 degenerate, 158 electric dipole. S quadrupole, 5 intensity. 21-27 longest-wavelength, alternant hydrocarbons, 74-75 magnetic dipole, 5 n- jr, 118-23... [Pg.281]

Figure 2.4. Calculated wavelength dependence of the longest wavelengths transition of polyenes on the number n of double bonds. FEMO results (—, right-hand scale) for completely delocalized jt electrons as well as for alternating double and single bonds with Vg = 2 eV, experimental points (—, right-hand sc e), and HMO results ( , left-hand scale). Figure 2.4. Calculated wavelength dependence of the longest wavelengths transition of polyenes on the number n of double bonds. FEMO results (—, right-hand scale) for completely delocalized jt electrons as well as for alternating double and single bonds with Vg = 2 eV, experimental points (—, right-hand sc e), and HMO results ( , left-hand scale).
Alternant hydrocarbons, 33, 86, 97, 112, 127. 167, 441. jT bond order, 441 excited stales. 17 first order Cl, 17, 54, 70 longest-wavelength transition. 74-75... [Pg.272]

See other pages where Transition longest-wavelength, alternant is mentioned: [Pg.254]    [Pg.33]    [Pg.74]    [Pg.50]    [Pg.309]    [Pg.14]    [Pg.248]    [Pg.11]    [Pg.33]    [Pg.74]   


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Longest

Transition wavelength

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