Transition bonds

If hvQ is small compared with kT, the partition function becomes kT/hvQ. The function kT jh which pre-multiplies the collision number in the uansition state theoty of the bimolecular collision reaction can therefore be described as resulting from vibration of frequency vq along the transition bond between the A and B atoms, and measures the time between each potential n ansition from reactants to product which will only occur provided that die activation energy, AEq is available. 

IRDLKS = infrared diode laser kinetic spectroscopy, investigation of the rotational structure of the l 2 band MW = microwave spectroscopy ED = electron diffraction ES = electronic spectroscopy, investigation of the rovibronic structure of electronic transitions bond angles calculated from isotopic shifts of the 03 bands of triatomic CAs are not presented here due to their large experimental error these values are reported in Section VI. 

The responses of the so-called smart drug delivery vehicles can be dissolu-tion/precipitation, sweUing/collapsing, hydrophilic/hydrophobic transition, bond... 

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