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Trans-RuCl

The complexes are made, usually as yellow perchlorates, by reaction of trans-[RuCl (R-TMC)]Cl, Ag(MeCgH S03) and aq. with HCIO [576, 616]. X-ray... [Pg.63]

Levason, W., Quirk, J. J., Reid, G., Smith, S. M., Synthesis, spectroscopic and redox properties of ruthenium complexes with selenoether macrocycles crystal structures of cis-[RuCl2([16]aneSe4)] and trans-[RuCl(PPh3)([16]aneSe4)]PF6 ([16]aneSe4 = 1,5,9,13-tetraselenacyclohexadecane). J. Chem. Soc., Dalton Trans. 1997, 3719-3724. [Pg.254]

The complexes cis- and /rn s-[RuCl2(dppm)2] undergo isomerization reactions induced by light, heat or oxidation to Ru111. The conversion trans - cis occurs thermally while cis -> trans occurs photochemically apparently by irradiation of the lowest lying d-d transition.1598 In water/alcohol mixtures photolysis of cis- or tranj-[RuCl2(dmpe)2] gives rro/u-[RuCl(OH2)(dmpe)2]+, while trans-[RuCl(DMSO)(dmpe)2]1 is always observed in DMSO. These results are consistent with the... [Pg.379]

The complexes trans-[RuCl(S2CNR2)2NO] (R2 = Me, Et, MePh, MeEt) are prepared by reaction of [RuCl3NO] with two equivalents of Na[S2CNR2]. A series of c s [RuX(S2CNR2)2NO] (X = Cl, Br, I, N02, SCN, N3, NCO, F) can be synthesized by treatment of the trans chloro compound with either HX or AgX. Heating some of these cis isomers to 160-210°C results in quantitative conversion to the trans isomer. Several cationic solvates frows-[Ru(S2CNR2)2NO(S)]+ (S = H20, MeOH) were also isolated and H and l3C NMR studies on all these compounds indicate stereochemical rigidity at ambient temperature.1308... [Pg.435]

RuHCl(cod) 2NH2NMe2] vi - [RuHLs]+ m trans-[RuCl,(PHPhj)4]... [Pg.458]

Related reactivity patterns have been described for the in sim formed complexes [RuCl(=C=C=C=C=CPh2)(j -C6Me6)(PR3)][PF6] (PRs = PMej, PMe.Ph. PMePhj) [359, 360], UC=CThvH, (, P.P.P)- (( ll,( ll,PPIi,)5 [PFg] [362], or trans-[RuCl(=C=C=C=C=CPh2)(dppm)2][PFg] [169, 216, 363], which readily add alcohols and amines (used as solvents) across the Cy=Cs bond. However, in the former case a competitive nucleophilic addition across the Ca=Cp double bond was also observed with methanol. [Pg.206]

The selective oxidative cleavage of styrene by 0 to benzaldehyde and formaldehyde has been achieved in the presence of [RuCl(dmpp)2]C10 or trans-[RuCl dmpp) ] as catalyst (1 atm 0, 22 °C, CH Cl ) [203]. [Pg.151]

See other pages where Trans-RuCl is mentioned: [Pg.39]    [Pg.120]    [Pg.120]    [Pg.208]    [Pg.210]    [Pg.210]    [Pg.210]    [Pg.356]    [Pg.357]    [Pg.665]    [Pg.666]    [Pg.30]    [Pg.43]    [Pg.90]    [Pg.354]    [Pg.442]    [Pg.385]    [Pg.391]    [Pg.617]    [Pg.546]    [Pg.164]    [Pg.227]    [Pg.564]    [Pg.210]    [Pg.326]    [Pg.356]    [Pg.391]    [Pg.3845]    [Pg.82]    [Pg.185]    [Pg.287]    [Pg.191]    [Pg.311]    [Pg.270]    [Pg.139]    [Pg.296]   
See also in sourсe #XX -- [ Pg.2 , Pg.2 , Pg.2 , Pg.2 , Pg.2 , Pg.2 , Pg.3 , Pg.3 , Pg.4 , Pg.4 , Pg.6 , Pg.11 ]



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