Trans effect apphcations

What is trans effect Explain the apphcations of trans effect using synthesis of Pt(II) complexes. 

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Alkenes, Allies, Arenes, and Alkanes. One of the most common apphcations of Oxone in organic synthesis is the in situ formation of dioxiranes fromketones (eq 1). Dioxrrane chemistry has grown significantly in recent years, particularly in the area of enantioselective epoxidation, and a wide variety of chiral ketones have been designed for this purpose. Notably, ketones (5 and 6) derived from fructose and glucose, respectively, have been shown to be effective catalysts for enantioselective epoxida-tions of a variety of trans-, trisubstituted, cis-, and terminal olefins with Oxone as primary oxidant (eqs 38 and 39). ... 

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