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TPEPICO spectroscopy

Similar values have been obtained for AHffMesSi ) from two independent studies. The bond dissociation enthalpy DHfMeaSi-SiMea) = 332 +12 kJ moC was obtained from a kinetic study on the very low pressure pyrolysis of hexamethyldisilane and the enthalpy of formation of trimethylsilyl ion, AHf (MeaSi ) = 617.3 + 2.3kJmor, was determined using threshold photoelectron-photoion coincidence spectroscopy (TPEPICO). Both data are related to AHf°(Me3Si ). [Pg.122]

TPEPICO threshold photoelectron-photoion coincidence TPES threshold photoelectron spectroscopy... [Pg.266]

Photoionization has a number of advantages over electron impact ionization, such as greater sensitivity and thresholds that are easier to define. In coincidence photoelectron techniques (e.g., photoelectron photoion coincidence spectroscopy, PEPICO, and threshold photoelectron photoion coincidence spectroscopy, TPEPICO), the photoelectron and the photoion formed in the ionization process are detected simultaneously, thus providing information on the nature and energies of the ionized products. ... [Pg.615]

See other pages where TPEPICO spectroscopy is mentioned: [Pg.1196]    [Pg.1196]    [Pg.279]    [Pg.279]    [Pg.133]    [Pg.964]   
See also in sourсe #XX -- [ Pg.1195 , Pg.1196 ]



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TPEPICO

Threshold photoelectron-photoion coincidence spectroscopy (TPEPICO

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