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Total Synthesis of Protomycinolide IV

The synthesis is based on the preparation of the C -Cg (212) and C -Cis (256) segments from a common chiral starting material, (5)-ethyl lactate (247), [Pg.28]

Alkyl Grignard reagents as well as organolithium reagents add to 11b with equal facility. The utility of this process is exemplified in the total synthesis of protomycinolide IV (335), a biogenetic precursor of macrolide antibiotics of the mycinamicin family [111]. [Pg.45]

The First Total Synthesis of Protomycinolide IV Yamaguchi, 1984 (Scheme 21) [59]... [Pg.27]

See other pages where Total Synthesis of Protomycinolide IV is mentioned: [Pg.351]    [Pg.654]    [Pg.28]    [Pg.351]    [Pg.654]    [Pg.28]   


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